I've heard some very glowing reviews of the DI2 group from various users. There are some very neat features like automatic trim adjustment on the front derailleur as you run through the rear gears. Apparently the shifting is lightening quick and more precise than you can believe.
I wonder about the battery life on the DI2 system. I did a century road ride back in May and ran into some poor old dude at a rest stop who's battery was dying. His bike disabled the front derailleur and he basically had to ride it like a 10 speed for the last 20 miles. I'm not sure the full story; perhaps he didn't charge it before the race or maybe he shifts excessively. But whatever it was, I bet I'd be in the same position because I never charge any battery powered thing in my life.
Some of the reviews I read say the battery lasts thousands of miles or months at a time. Which is impressive.
Rumor is Shimano will have a DI2 system for MTB out in 2015...